Raman analysis of chemical substitution of Cd atoms by Hg in CdSe quantum dots and rods

Sergei A. Cherevkov; Alexander V. Baranov; Elena V. Ushakova; Alexander P. Litvin; Anatoly V. Fedorov; Anatoly V. Prudnikau; Mikhail V. Artemyev

doi:10.1117/1.OE.55.1.017104

18 January 2016 Raman analysis of chemical substitution of Cd atoms by Hg in CdSe quantum dots and rods

Sergei A. Cherevkov, Alexander V. Baranov, Elena V. Ushakova, Alexander P. Litvin, Anatoly V. Fedorov, Anatoly V. Prudnikau, Mikhail V. Artemyev

Author Affiliations +

Optical Engineering, Vol. 55, Issue 1, 017104 (January 2016). https://doi.org/10.1117/1.OE.55.1.017104

Abstract

We investigate nanocrystals of ternary compounds Cd_XHg_1−XSe with 0 < X < 1 using a Raman scattering technique at room temperature. We obtained the correlation between nanocrystal (NC) chemical composition and the frequencies of CdSe-like LO and the HgSe-like TO and LO-modes. It is shown that the crystalline structure of the original CdSe NCs used for Cd / Hg substitution, either zinc blende or wurtzite, strongly affects the structural properties of the resultant Cd_XHg_1−XSe quantum dots and rods.

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Sergei A. Cherevkov, Alexander V. Baranov, Elena V. Ushakova, Alexander P. Litvin, Anatoly V. Fedorov, Anatoly V. Prudnikau, and Mikhail V. Artemyev "Raman analysis of chemical substitution of Cd atoms by Hg in CdSe quantum dots and rods," Optical Engineering 55(1), 017104 (18 January 2016). https://doi.org/10.1117/1.OE.55.1.017104

Published: 18 January 2016

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