Paper
24 June 1993 Damage to copper mirrors by high-power CO2 laser radiation
A. Angenent, C. R. Haas, Joachim Koch, Ernst-Wolfgang Kreutz, David A. Wesner
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Abstract
A focused, cw CO2 laser is used to irradiate polished Cu mirrors at power densities near 40 kW/cm2. Uncoated mirrors and mirrors having a reflection-enhancing Au coating with a protective Y2O3 layer are tested. During irradiation in-situ measurements of the temperature distribution in the surface are made and the morphology is monitored by interferometry. Chemical changes are determined by ex-situ x-ray photoemission and scanning Auger measurements. Damage to uncoated mirrors is connected with irreversible deformation, an increase in thermal gradients under irradiation (attributable to increased absorption), and oxidation of the surface layer, with formation of Cu2O and CuO. While the whole surface becomes oxidized, the effect is strongest in the laser focus, where an enhanced carbon content is also found. Similar thermal and morphological changes occur in coated mirrors under analogous irradiation conditions, but the relatively inert Y2O3 protective layer is not chemically changed. Structural changes are present in the surface and may contribute to the changed absorption.
© (1993) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
A. Angenent, C. R. Haas, Joachim Koch, Ernst-Wolfgang Kreutz, and David A. Wesner "Damage to copper mirrors by high-power CO2 laser radiation", Proc. SPIE 1848, 24th Annual Boulder Damage Symposium Proceedings -- Laser-Induced Damage in Optical Materials: 1992, (24 June 1993); https://doi.org/10.1117/12.147430
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KEYWORDS
Mirrors

Copper

Carbon dioxide lasers

Absorption

Temperature metrology

Oxides

Chemical analysis

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