Intermolecular potential for highly excited molecules

Alexander D. Bykov; Valentina N. Stroinova

doi:10.1117/12.545200

12 January 2004 Intermolecular potential for highly excited molecules

Alexander D. Bykov, Valentina N. Stroinova

Proceedings Volume 5311, 14th Symposium on High-Resolution Molecular Spectroscopy; (2004) https://doi.org/10.1117/12.545200
Event: 14th Symposium on High-Resolution Molecular Spectroscopy, 2003, Krasnoyarsk, Russian Federation

Abstract

The general expressions for intermolecular potential are obtained on the base of the symmetrical approach. The convergence of intermolecular potential representations to be used for practical relaxation parameter calculations is investigated. It is found the series of intermolecular potential over inverse orders of intermolecular distance are divergent. In this work the technique for the summing of divergent series is supposed. The vibrational dependence of intermolecular potential is analyzed.

Citation Download Citation

Alexander D. Bykov and Valentina N. Stroinova "Intermolecular potential for highly excited molecules", Proc. SPIE 5311, 14th Symposium on High-Resolution Molecular Spectroscopy, (12 January 2004); https://doi.org/10.1117/12.545200

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