Paper
15 April 2016 Electro-spraying and ultra-violet light curing of polydimethylsiloxane to fabricate thin films for low-voltage dielectric elastomer actuators
Florian M. Weiss, Gabor Kovacs, Tino Töpper, Bekim Osmani, Vanessa Y. F. Leung, Bert Müller
Author Affiliations +
Abstract
Currently, dielectric elastomer actuators (DEA) are mainly based on micrometer-thin polymer films and require operating voltages of several hundred volts. In medical applications, however, voltages as low as a few tens of volts are required. To this end, we prepared nanometer-thin dielectric elastomer layers. It is demonstrated that alternating current, electro-spray deposition allows for the fabrication of homogenous, flat, nanometer-thin polydimethylsiloxane (PDMS) films. The growth of the PDMS with average number molecular weights ranging from 800 to 62,700 g/mol, at a constant flow rate of 267 nL/s, was in situ monitored by means of spectroscopic ellipsometry. The Cauchy layer model used for data interpretation may only be applied to flat PDMS layers. Thus, in the present study the droplet morphology was also determined by atomic force microscopy. Spectroscopic ellipsometry does allow for the qualitative determination of the thin film morphology. However, for high molecular weight polymers the precise measurement during deposition is challenging. Independent of the molecular weight, the roughness of the deposited PDMS films considerably smoothens during the ultra-violet radiation treatment. After curing, the electro-sprayed nanometer-thin PDMS films are homogeneous enough to qualify for the fabrication of low-voltage DEA.
© (2016) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Florian M. Weiss, Gabor Kovacs, Tino Töpper, Bekim Osmani, Vanessa Y. F. Leung, and Bert Müller "Electro-spraying and ultra-violet light curing of polydimethylsiloxane to fabricate thin films for low-voltage dielectric elastomer actuators", Proc. SPIE 9798, Electroactive Polymer Actuators and Devices (EAPAD) 2016, 97983C (15 April 2016); https://doi.org/10.1117/12.2220786
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KEYWORDS
Polymers

Ultraviolet radiation

Spectroscopic ellipsometry

Dielectric elastomer actuators

Polymer thin films

Data modeling

Ellipsometry

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