In lithography, resist patterns are fabricated through chemical reactions induced by radiation. In the highly resolving lithography such as extreme ultraviolet (EUV) lithography, the stochastically generated defects, called stochastic defects, are a serious concern. In this study, the variation of resist polymer caused by stochastic effects was investigated, assuming line-and-space patterns to assess the defect risks. Using a half pitch, a sensitivity, a thermalization distance, a total sensitizer concentration, and a standard deviation of the number of protected units per polymer molecule as variables, the resist pattern formation was simulated on the basis of the sensitization and reaction mechanisms. The risks of stochastic pinching and bridging were clarified from the viewpoint of the variation of resist polymer in terms of the relationships to a half pitch, a sensitivity, a thermalization distance, a total sensitizer concentration, and a standard deviation.
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