We discuss the importance of low emittance and temperature stability for solar-selective high-temperature coatings. We show experimentally that high stagnation temperatures can be achieved by reducing the coating emissivity below previously-obtained values. We have investigated amorphous hydrogenated carbon (a-C:H) and silicon-carbon alloy (a-SixCi-x:H) films prepared by magnetically-enhanced glow discharge decomposition. In the latter case, we have prepared alloys from acetylene, ethylene and methane mixed with silane. We have shown by electron microprobe analysis that the atomic C/Si ratio in the film is the same as that in the gas. We show that both the emittance of a-C:H films and their high temperature stability can be enhanced by annealing in vacuum. The film properties change substantially in the first hour of heat treatment at 500°C, before stabilizing after about 24 hours. Thereafter, the properties do not change during a further 300 hours of heat treatment. The heat -stabilized films, when placed on copper substrates and used in non-concentrating systems, have been shown to yield stagnation temperatures up to 459°C in preliminary experiments. The a-SixC1-x :H films investigated have the potential to provide lower emittance coatings than the a-C:H alloys which are currently employed in composite metal-amorphous semiconductor films. The use of silicon/carbon alloys also provides greater flexibility in grading profiles for the composite films, permitting greater control in the trade-off between high solar absorptance and low emissivity.
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