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The Zr - free fluoride glass termed BIZYbT and based on the combination of Baryum, Indium, Zinc, Ytterbium and
Thorium fluorides hasbeen optimized in orderto decrease thecriticalcoolingrate and make this glass suitablefor fiberdrawing.
The lowest value of 5°C/mn has been obtained and is comparable to the classical ZBLAN fluoride glass.
Jacques Lucas,Isabelle Noiret-Chiaruttini,Gilles Fonteneau,P. Christensen, andSeiko Mitachi
"New multicomponent fluoride glasses with low critical cooling rates for optical fibers", Proc. SPIE 1228, Infrared Fiber Optics II, (1 May 1990); https://doi.org/10.1117/12.18627
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Jacques Lucas, Isabelle Noiret-Chiaruttini, Gilles Fonteneau, P. Christensen, Seiko Mitachi, "New multicomponent fluoride glasses with low critical cooling rates for optical fibers," Proc. SPIE 1228, Infrared Fiber Optics II, (1 May 1990); https://doi.org/10.1117/12.18627