In the almond industry, the presence of bitter almonds in processed batches is a common problem that causes not only unpleasant flavors but also problems in the product commercialization. This research group has previously demonstrated the potential of Near Infrared Spectroscopy (NIRS) to detect adulterated almond batches; however, since NIRS provides an average spectrum of each batch, it does not enable to identify each individual bitter almond. Hyperspectral Imaging (HSI), which integrates both the spectral and spatial dimensions, enables to know the spatial distribution of the different physico-chemical characteristics, favoring the individual identification of the different compounds in the sample. The aim of this study was to evaluate the feasibility of using a HSI system for the identification of bitter almonds in sweet almond batches. Samples were analyzed using a HSI camera working in the spectral range 946.6–1648.0 nm and Partial Least Squares Discriminant Analysis (PLS-DA) was applied. A classification success over the 99% was obtained in cross-validation and the pixel-by-pixel validation identified correctly between the 61 – 85% of the adulterations. The results confirm that HSI can be considered a promising approach for the classification of almonds by bitterness, allowing the identification of each single bitter almond present in the batch.
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