Paper
23 January 2023 Study on corrosion process and mechanism of fluoride laser glass fiber
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Proceedings Volume 12556, AOPC 2022: Optoelectronics and Nanophotonics; 125560N (2023) https://doi.org/10.1117/12.2646324
Event: Applied Optics and Photonics China 2022 (AOPC2022), 2022, Beijing, China
Abstract
Corrosion behaviors of the precursor glass (ZBLAN) of fluoride fibers in solutions of different pH values are studied. After seven d of corrosion, the infrared transmittance of ZBLAN decreases to almost 0 in acidic and neutral environments. However, there is no significant loss of transmittance in an alkaline environment. Similarly, the surfaces of the samples in acidic or neutral environments are severely corroded, whereas in alkaline environments, they are slightly corroded. In addition, it is found that samples corroded in neutral water have a complete crystallization phenomenon, wherein complex crystal phases emerged. However, no characteristic peaks of the crystal phase are observed in the samples corroded in the acidic and alkaline environments. The corrosion mechanism is investigated based on the change in the concentration of ZBLAN constituent elements in the solution via inductively coupled plasma (ICP) emission spectrometry.
© (2023) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Meng Cai, Longfei Zhang, Feng Guan, Wenkai Zhao, Long Zhang, and Yiguang Jiang "Study on corrosion process and mechanism of fluoride laser glass fiber", Proc. SPIE 12556, AOPC 2022: Optoelectronics and Nanophotonics, 125560N (23 January 2023); https://doi.org/10.1117/12.2646324
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KEYWORDS
Glasses

Corrosion

ZBLAN

Crystals

Transmittance

Chemical elements

Fiber lasers

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