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Small copper particles within zeolite (mordenite) matrix produced by copper ion reduction were studied. Variation of SiO2/Al2O3 molar ratio of mordenite does not change crystal structure, but results in different ionic properties. A change of SiO2/Al2O3 ratio leads to transformation of the plasmon resonance from a classical peak to a shoulder in the same wavelength range. These features were simulated by the Mie theory, and calculations outlined additional absorption bands those consistent with the experiment.
Vitalii P. Petranovskii,Valerij S. Gurin, andJose Victor Tamariz Flores
"Plasmon resonance of copper nanoparticles within zeolites: the effect of matrix composition and agglomeration temperature", Proc. SPIE 4467, Complex Mediums II: Beyond Linear Isotropic Dielectrics, (9 July 2001); https://doi.org/10.1117/12.432951
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Vitalii P. Petranovskii, Valerij S. Gurin, Jose Victor Tamariz Flores, "Plasmon resonance of copper nanoparticles within zeolites: the effect of matrix composition and agglomeration temperature," Proc. SPIE 4467, Complex Mediums II: Beyond Linear Isotropic Dielectrics, (9 July 2001); https://doi.org/10.1117/12.432951