Paper
16 May 2005 Orientation dependence of the properties of PZN-4.5%PT relaxor single crystals
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Abstract
Relaxor ferroelectric PZN-xPT and PMN-xPT single crystals exhibit excellent electromechanical coupling properties that depend on crystallographic orientations. In this study compressive stress and electric field were applied to relaxor single crystals [Pb(Zn1/3Nb2/3)O3]0.955-[PbTiO3]0.045 (PZN-4.5%PT) in a series of crystal orientations between <001> and <111>, and the corresponding strain and electric displacement were measured. It was found that as the angle of the orientation cut is rotated from <001> to <111>, the piezoelectric coefficient d33 drops and hysteresis increases dramatically. A crystal variant based approach was used to model the piezoelectric coefficients and remnant electric displacement. The bipolar electro-mechanical response of these crystals is presented. Observed hysteresis and nonlinear phenomena related to polarization reorientation and phase transitions is discussed. In actuator design and performance control, these results give a guideline regarding appropriate external fields in order to prevent depolarization, heat generation and damage.
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T. Liu and C. S. Lynch "Orientation dependence of the properties of PZN-4.5%PT relaxor single crystals", Proc. SPIE 5761, Smart Structures and Materials 2005: Active Materials: Behavior and Mechanics, (16 May 2005); https://doi.org/10.1117/12.606031
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KEYWORDS
Crystals

Polarization

Switching

Nonlinear crystals

Crystallography

Niobium

Actuators

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