Organometallic self-organized nanomaterials for nonlinear optics

William E. Douglas; Larissa G. Klapshina; Ilya S. Grigoryev; Tatyana I. Lopatina; Vladimir V. Semenov; Georgy A. Domrachev; Boris A. Bushuk; Sergei B. Bushuk; Andrey Yu. Lukianov; Andrey V. Afanas'ev; Robert E. Benfield; Alexey I. Korytin

doi:10.1117/12.608704

7 July 2005 Organometallic self-organized nanomaterials for nonlinear optics

William E. Douglas, Larissa G. Klapshina, Ilya S. Grigoryev, Tatyana I. Lopatina, Vladimir V. Semenov, Georgy A. Domrachev, Boris A. Bushuk, Sergei B. Bushuk, Andrey Yu. Lukianov, Andrey V. Afanas'ev, Robert E. Benfield, Alexey I. Korytin

Author Affiliations +

Proceedings Volume 5840, Photonic Materials, Devices, and Applications; (2005) https://doi.org/10.1117/12.608704
Event: Microtechnologies for the New Millennium 2005, 2005, Sevilla, Spain

Abstract

Novel nonlinear optical polymeric film-producing nanocomposites based on bis(arene)chromium complexes incorporated into a CN-containing matrix have been developed. Polymer-precursors were prepared by the reaction of Cr(EtnC6H6?n)2 mixtures (n = 1,2,3) with CN-containing vinyl monomers (acrylonitrile, crotononitrile and ethylcyanoacrylate). The nonlinear-optical measurements in the absence of external electrical fields showed a "natural" anisotropy resulting from self-organization taking place during the film formation process. Measurements by the spectrally-resolved two-beam coupling method confirmed that the test composites exhibited a significant cubic nonlinear optical susceptibility of the ultra-fast electronic type.

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William E. Douglas, Larissa G. Klapshina, Ilya S. Grigoryev, Tatyana I. Lopatina, Vladimir V. Semenov, Georgy A. Domrachev, Boris A. Bushuk, Sergei B. Bushuk, Andrey Yu. Lukianov, Andrey V. Afanas'ev, Robert E. Benfield, and Alexey I. Korytin "Organometallic self-organized nanomaterials for nonlinear optics", Proc. SPIE 5840, Photonic Materials, Devices, and Applications, (7 July 2005); https://doi.org/10.1117/12.608704

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