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Low-resistive and stable p-type ZnSe crystal can be grown by the temperature difference method under controlled vapor pressure (TDM-CVP) of Zn in the solution of Se. The properties of a p-ZnSe crystal grown under optimum Zn pressure, which was about 7.2 atm at the growth temperature of 1050°C, show best value resulting in the suppression of the nonstoichiometric point defects. As a result, a p-n junction can be formed by the Ga diffusion under the control of Se pressure in the p-type ZnSe crystal and a high efficiency pure blue LED can be realized.
Jun-ichi Nishizawa andYasuo Okuno
"Crystal Growth Of p-ZnSe And ZnSe p-n Junctions", Proc. SPIE 0796, Growth of Compound Semiconductors, (20 April 1987); https://doi.org/10.1117/12.940998
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Jun-ichi Nishizawa, Yasuo Okuno, "Crystal Growth Of p-ZnSe And ZnSe p-n Junctions," Proc. SPIE 0796, Growth of Compound Semiconductors, (20 April 1987); https://doi.org/10.1117/12.940998