24 March 2015 Improved power conversion efficiency for bulk heterojunction solar cells incorporating CdTe-CdSe nanoheterostructure acceptors and a conjugated polymer donor
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Abstract
We report photovoltaic devices based on composites of a branched nanoheterostructure containing a CdTe core and CdSe arms, CdTe(c)-CdSe(a), combined with either poly(3-hexylthiophene), P3HT, or poly[2,6-(4,4-bis-(2-ethylhexyl)-4H-cyclopenta[2,1-b;3,4-b′]dithiophene)-alt-4,7-(2,1,3-benzothiadiazole)], PCPDTBT, with solar power conversion efficiencies of 1.2% and 1.8%, respectively. A comparison with previously reported composite devices of a related branched nanoheterostructure: CdSe(c)-CdTe(a) reveals an improved device performance that is attributed to a better electron percolation pathway provided by the dominant, higher electron affinity CdSe arms of the nanoheterostructures.
© 2015 Society of Photo-Optical Instrumentation Engineers (SPIE) 1947-7988/2015/$25.00 © 2015 SPIE
Smita Dayal, Haizheng Zhong, Nikos Kopidakis, Gregory D. Scholes, and Garry Rumbles "Improved power conversion efficiency for bulk heterojunction solar cells incorporating CdTe-CdSe nanoheterostructure acceptors and a conjugated polymer donor," Journal of Photonics for Energy 5(1), 057409 (24 March 2015). https://doi.org/10.1117/1.JPE.5.057409
Published: 24 March 2015
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Cited by 7 scholarly publications.
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KEYWORDS
Polymers

Solar cells

Heterojunctions

Composites

Electron transport

Energy efficiency

Photovoltaics

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