We have studied the effects of planar, lamellar, and random nanostructured metal-dielectric environments on spontaneous emission and energy transfer concentration quenching of HITC laser dye. We found an inhibition of the concentration quenching in vicinity of metal, which was stronger in nanostructured substrates than in plain geometries. It was shown that the same substrates, which boosted spontaneous emission, also inhibited the concentration quenching. The effect is discussed in terms of the Förster radius affected by losses.
Work at LLNL was performed under the auspices of the U.S. Department of Energy by LLNL under Contract DE-AC52-07NA27344
We report on the optical properties of nanoporous gold leaf (NPGL) metamaterials consisting of single and multiple-fold layers, and having different pore and ligament sizes. Due to their complex structure, such metamaterials have a unique optical property, which distinguishes them from homogeneous gold films. Thus, the transmission spectra of NPGLs feature two characteristic peaks positioned at ~ 490 nm and ~560 nm to 605 nm. The most notable result of this study is that the optical properties of NPGLs can be tuned by changing the dielectric environment and by applying voltage in an electrochemical cell.
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