A method for determining the quantum efficiency and core propagation loss in thulium-doped silica fibres is presented. The results provide evidence that thermal management of the fibre is a critical experimental parameter for achieving accurate predictions of fibre performance with this method. By submerging this ‘nested-ring’ fibre in a temperature-controlled water bath, a quantum efficiency of 1.93 was measured, providing evidence that the high doping level is successfully promoting the ‘two-for-one’ cross-relaxation process. Measurements of core propagation loss gave 0.15 dB/m, which is suggestive that core propagation loss presents a major issue for efficient power scaling to the kilowatt regime.
The free-running and acousto-optically Q-switched laser properties of Er:YAP crystal, which is appropriate for generation at 2.8 μm, are presented. The sample of Er:YAP (concentration 5 at.% of Er3+, thickness 9 mm) had plan-parallel polished faces without antireflection coatings. The excitation of Er:YAP crystal was carried out by a laser diode emitting at 973 nm and working in a pulsed regime (pulse duration 5 ms, repetition rate 10 Hz). The laser resonator was hemispherical, 150 mm in length, with a flat pumping mirror (HR @ 2.8 μm) and a spherical output coupler (r = 150 mm, R = 95 % @ 2.5 - 2.9 μm). In the free-running laser regime, the maximum output power of 156 mW and slope efficiency of 17 % with respect to absorbed pumped power were obtained. To obtain a Q-switching laser operation, the acousto-optic germanium element was inserted between the Er:YAP crystal and the output coupler. The shortest pulse duration of 36.2 ns with a repetition rate of 10 Hz and maximum pulse energy of 0.43 μJ were obtained. The emitted laser wavelength of 2.8 μm can be used as a pump source at room-temperature for Fe:ZnSe or in mid-infrared spectroscopy.
In this work, the spectroscopy and laser characteristics of the ceramic Er:Y2O3 are presented in the temperature range from 80 to 300 K. Er:Y2O3 ceramic (5 at. % of Er3+, Baikowski Co., Ltd.) had the form of a rectangular block (thickness 9 mm) with plan-parallel polished faces (cross-section 3 × 3 mm) without anti-reflection coatings. The active medium was attached to the copper cold finger of the liquid nitrogen cryostat in a vacuum chamber. The pumping of Er:Y2O3 was carried out by radiation from fibre-coupled laser diode (pulse duration 3 ms, repetition rate 16.6 Hz, wavelength 972 nm). All spectroscopy measurements – transmission, fluorescence and up-conversion spectra together with fluorescence decay times at 4I11/2 and 4I13/2 were obtained in the temperature range from 80 to 300 K. The fluorescence decay time of manifold 4 I11/2 (upper laser level) is slightly increasing with rising temperature from 325 μs (80 K) to 342 μs (170 K) and then its decreasing to 295 μs (300 K). On the other hand, the decay time of lower laser lever 4I13/2 is increasing together with a rising temperature from 3.6 ms (80 K) to 4.6 ms (300 K). Moreover, it was obvious that with decreasing temperature, the intensity of green up-conversion radiation (564 nm) increased. For laser experiments a hemispherical resonator (80 mm in length) with a flat pumping mirror (HT < 94 % @ 960 - 980 nm and HR < 99 % @ 2.65 - 3 μm) and spherical output coupler (r = 100 mm, R = 95 % @ 2.65 - 2.95 μm) were used. Er:Y2O3 laser was operated in the pulsed regime to prevent damage to the active medium, the highest slope efficiency 9.5 % (with respect to absorbed power) and maximum output power of 83 mW were reached at a duty cycle of 5 %. With rising temperature the slope efficiency was decreasing down to 5 % at 300 K, on the other hand the laser threshold with respect to absorbed mean power was increased from 50 mW (80 K) to 150 mW (300 K). The emitted laser wavelength by the Er:Y2O3 laser was slightly changed due to the heating of the active medium from 2744 nm (at 80 K) to 2742 nm (at 300 K). The erbium-doped ceramic active media can be used as an alternative to crystals because of its easier fabrication compared to single-crystal sesquioxides, which require high melting point and special materials for crucible during growing process.
In this work, the spectroscopy and laser characterization of Er,Pr-doped GGAG crystal was carried out in the temperature range from 80 K to 300 K. The tested Er,Pr:GGAG (13.4 at. % of Er3+ and 0.09 at. % of Pr3+, thickness 3.3 mm) crystal in form of disc had plan-parallel polished faces without anti-reflection coatings. During measurements, the Er,Pr:GGAG was attached to temperature controlled copper holder and it was placed in a cryostat vacuum chamber. The Er,Pr:GGAG was pumped by a fibre-coupled laser diode radiation (pulse duration 1 ms, repetition rate 20 Hz, wavelength 962 nm). The transmission and fluorescence spectra together with the fluorescence decay times at the upper (4I11/2) and lower (4I13/2) laser level were measured in the temperature range from 80 K to 300 K. The fluorescence decay time of manifold 4I11/2 (upper laser level) is slightly increasing with rising temperature from 325 μs (80 K) to 341 μs (160 K) and then its decreasing to 295 μs (300 K). On the other hand, the intensity of up-conversion radiation was increasing with decreasing temperature. During the laser experiments a hemispherical resonator (150 mm in length) with flat pumping mirror (HT < 94 % and HR < 99 % @ 960 - 980 nm) and spherical output coupler (r = 150 mm, R = 97.5 % @ 2.65 - 2.95 μm) was used. The tunability of emitted laser wavelength at 80 and 300 K was tested using MgF2 birefringent plate, and several laser lines at 2874 nm, 2832 nm, 2805 nm, 2718 nm, and 2702 nm were obtained. In the pulsed laser regime, the highest slope efficiency 16 % (with respect to absorbed power) and maximum output power 118 mW were reached at 5 % duty cycle. The laser radiation generated by Er,Pr:GGAG laser (wavelength 2.9 μm) is close to the absorption peak of water (3 μm) and it can be tuned in a wide spectral range which could be advantageous for various applications in medicine or spectroscopy.
The spectroscopic and laser properties of Er:GGAG active medium, in temperature range from 80 K to 300 K, are presented in this work. The sample of Er:GGAG (20 at. % of Er3+) crystal had face-polished plan-parallel faces without anti-reflection coatings (thickness 3.6 mm). During all experiments the Er:GGAG was attached to temperature controlled copper holder and it was placed in a vacuum chamber. The transmission and emission spectra together with the fluorescence decay time were measured depending on temperature. The excitation of Er:GGAG was carried out by a fibre-coupled laser diode radiation (pulse duration 2 ms, repetition rate 25 Hz, wavelength 964 nm). Laser resonator was hemispherical, 100 mm in length with flat pumping mirror (HR @ 2.95 μm) and a spherical output coupler (r = 100 mm, R = 97.5 % @ 2.65 - 2.95 μm). The tunability of laser at 300 K was tested using MgF2 birefringent filter and several laser lines at several spectral bands 2800 – 2822 nm, 2829 – 2891 nm, and 2917 – 2942 nm were obtained. The fluorescence decay time of manifold 4I11/2 (upper laser level) is slightly increasing with rising temperature from 482 μs (80 K) to 466 μs (300 K) on the other hand the intensity of up-conversion radiation was increasing with decreasing temperature. In the pulsed laser regime, the highest slope efficiency with respect to absorbed energy 9 % and the maximum output energy 2.6 mJ were reached at 5 % duty cycle. The laser radiation generated by Er:GGAG laser (2.94 μm) is close to the absorption peak of water (3 μm) thus this wavelength can be used in medicine or spectroscopy.
The free-running and passive Q-switched laser properties of Er,La:SrF2-CaF2 crystal, that is appropriate for generation at 2.74 μm, are presented. The sample of Er,La:SrF2-CaF2 (composition 4 wt.% of ErF3, 12 wt.% of LaF3, 77 wt.% of CaF2, and 7 wt.% of SrF2, thickness 8.2 mm) had plan-parallel polished faces without anti-reflection coatings. The excitation of Er,La:SrF2-CaF2 was carried out by a 975 nm laser diode radiation in pulsed (pulse duration 1 ms, repetition rate 10 Hz) and CW mode. Laser resonator was hemispherical, 10 mm or 45 mm in length with flat pumping mirror (HR @ 2.7 μm) and spherical output coupler (r = 50 mm, R = 97.5 % or R = 95 % @ 2.5 - 2.8 μm). For CW mode of operation of Er,La:SrF2-CaF2 the highest obtained slope efficiency was 20.2 %. The maximum output power 0.35 W was achieved in this case. With semiconductor saturable absorber (SESAM) in laser resonator the shortest pulse duration of 33.4 ns with repetition rate 50 kHz was obtained. The maximal pulse energy 5.4 μJ with peak power 122 W was reached for 44.2 ns pulse duration. Since the emitted laser wavelength 2.74 μm is relatively close to absorption peak of water located at 3 μm, one of the Er,La:SrF2-CaF2 laser possible usage should be in medicine and spectroscopy.
The spectroscopic and laser properties of Er:YLF crystal, that is appropriate for generation at 2.8 μm, in temperature range 80 - 300 K are presented. The sample of Er:YLF (6 at. % of Er3+) had face-polished plan- parallel faces without anti-reflection coatings (thickness 9 mm). During experiments the Er:YLF was attached to temperature controlled copper holder and it was placed in vacuum chamber. The transmission and emission spectra together with the fluorescence decay time were measured depending on temperature. The excitation of Er:YLF was carried out by a laser diode radiation (pulse duration 5 ms, repetition rate 10 Hz, pump wavelength 972 nm). Laser resonator was hemispherical, 100 mm in length with flat pumping mirror (HR @ 2.8 μm) and spherical output coupler (r = 100 mm, R = 95 % @ 2.65 - 2.85 μm). The tunability of laser at 80, 200 and 300 K was tested using MgF2 birefringent filter and several laser lines in wavelength range from 2709 nm to 2860 nm were observed. The fluorescence decay time of manifold 4I11/2 (upper laser level) became shorter and intensity of up-conversion radiation was increasing with decreasing temperature. In pulsed regime, the highest slope efficiency with respect to absorbed mean power 23 % and the maximum output energy 12.5 mJ were reached. The laser radiation generated by Er:YLF laser (2.81 μm) is close to absorption peak of water (3 μm) thus this wavelength can be use in medicine and spectroscopy.
The spectroscopy properties and lasing of diode pumped Tm-doped strontium molybdate SrMoO4 single crystal were investigated at room temperature. The Tm:SrMoO4 crystal was grown by modified Stepanov method (2 wt.% of TmNbO4 in the melt). The tested Tm:SrMoO4 sample was cut from the grown crystal boule perpendicularly to growth direction 100. For spectroscopy and laser experiments 4.2mm thick plane-parallel face-polished plate (without AR coatings) was used. A fiber-coupled laser diode operating at wavelength 793nm was used for longitudinal Tm:SrMoO4 pumping which corresponds to 3H4 level excitation. Fluorescence spectra measurement showed strong emission in vicinity of 1.8 μm (3F4 → 3H6 transition), and also significant emission close to wavelengths 1.45 μm (3H4 → 3F4 transition) and 2.3 μm (3H4 → 3H5 transition). The lasing was successfully reached for all these three transitions and output characteristics were measured. The pumping laser diode was operating in the pulsed regime with a low duty cycle. The 145mm long semi-hemispherical laser resonator consisted of flat pumping mirror (HT @ 0.79 μm) and curved (r = 150mm) output coupler. For each lasing transition the particular set of resonator mirrors was used to reach high reflexivity of pumping mirror and output coupler transmission 0.5% at laser operation wavelength. The obtained laser emission wavelengths were 1.95 μm, 1.45 & 1.49 μm, and 2.30 μm. In spite of low laser slope efficiency in respect to absorbed pumping power (0.45% for 3H4 → 3F4 transition, 0.50% for 3F4 → 3H6 transition and 0.83% for 3H4 → 3H5 transition), results obtained are promising for further development of diode-pumped laser at 2.3 μm spectral region.
The spectroscopic and laser properties of Er:YAP crystal, that is appropriate for generation at 2.7 μm, in temperature range 78 - 400 K are presented. The sample of Er:YAP (1 at. % of Er3+) had face-polished plan-parallel faces without anti-reflection coatings (thickness 4.47 mm). During experiments the Er:YAP was attached to temperature controlled copper holder and it was placed in vacuum chamber. The transmission and emission spectra together with the fluorescence decay time were measured depending on temperature. The Er:YAP crystal was longitudinally pumped by radiation from laser diode that works in pulse regime (repetition rate 66.6 Hz, pulse duration 1.5 ms, pump wavelength 972.5 nm) or in CW regime. Laser resonator was hemispherical, 145 mm in length with flat pumping mirror (HR @ 2.7 μm) and spherical output coupler (r = 150 mm, R = 95 % @ 2.5 - 2.8 μm). The fluorescence decay time of manifold 4I11/2 (upper laser level) became shorter and intensity of up-conversion radiation was increasing with decreasing temperature. In pulsed regime, the highest slope efficiency with respect to absorbed mean power was 1.27 % at 78 K. The maximum output of mean power was 3.5 mW at 78 K, i.e. 8.7 times higher than measured this value at 300 K. The maximal output power 27 mW with slope efficiency up to 3.5 % was achieved in CW. The radiation generated by Er:YAP laser (2.73 μm) is close to absorption peak of water (3 μm) thus this wavelength can be use in medicine and spectroscopy.
In this work the temperature dependence of spectroscopic and laser properties of new ac-
tive medium Tm:SBN (Strontium-Barium Niobate, SrxBa1−xNb2O6, x = 0.61). The tested sample of Tm:SBN
(2 wt. % of Tm2O3) appropriate for generation of laser radiation at 1.88 μm had plan-parallel polished faces
without anti-reflection (thickness 6.65 mm). During spectroscopy and laser experiments the Tm:SBN was at-
tached to temperature-controlled copper holder and was placed in a vacuum chamber. The transmission and
emission spectra of Tm:SBN and the fluorescence decay time were measured depending on temperature range
80 - 350 K. The fluorescence decay time was measured to be 3.5 ms and 2.8 ms at 80 and 350 K, respectively.
Longitudinal excitation of Tm:SBN was carried out by a fibre-coupled laser diode (pulse duration 10 ms, rep-
etition rate 10 Hz, pump wavelength 793 nm). The laser resonator was hemispherical, 146 mm long, with flat
pumping mirror (HR @1.8 - 2.1 μm) and spherical output coupler (r = 150 mm, R = 97.5 % @1.8 - 2.1 μm).
The Tm:SBN laser properties were investigated at temperature range 80 - 300 K. The highest slope efficiency
with respect to absorbed pumped power was 3 % at 80 K. The maximum output peak amplitude power was
0.12 W at 80 K, i.e. 3.2 times higher than it was measured at 200 K. Tunability of laser wavelength at 80 K
in the range of 1827 - 1962 nm was obtained by using SiO2 birefringent filter. At 300 K, wavelength tunability
reached 1859 - 1970 nm. Thus, the new Tm:SBN crystal can be an useful laser material in the region of 2 μm.
Glass matrix doped with rare-earth ions is a promising laser active medium for high power laser systems. Due to amorphous structure of glasses the absorption and emission spectra lines are broader in comparison with crystalline materials thus pumping radiation can be absorbed efficiently, moreover much broader gain bandwidth is suitable for generation of ultra-short pulses. Another advantage of the glass matrix is the possibility to fabricate large volume ingots and simultaneously preservation of sufficient optical quality. The lower thermal conductivity of glasses can be compensated by geometry of the active medium for instance shaped into fibres or discs. We present temperature dependence of spectroscopic and laser properties of newly developed Er, Yb - doped potassium-lanthanum phosphate glass, which is appropriate for generation of radiation at 1.53 μm. The sample of Er,Yb:KLaP glassy mixture was cut into disc shape with dimensions of 2.5 mm (thickness) and 5 mm (diameter) and its faces were polished plan-parallelly without being anti-reflection coated. The temperature dependence of the transmission and emission spectra Er,Yb:KLaP together with the fluorescence decay time were measured the temperature range from 80 to 400 K. The fluorescence lifetime of manifold 4I13/2 (upper laser level) prolonged and the intensity of up-conversion radiation decreased with decreasing temperature. The longitudinal excitation of Er,Yb:KLaP was carried out by a fibre-coupled laser diode (pulse duration 2 ms, repetition rate 10 Hz, pump wavelength 969 nm). Laser resonator was hemispherical, with flat pumping mirror (HR @ 1.5 μm) and spherical output coupler (R = 98 % @ 1.5 - 1.6 μm). The Er,Yb:KLaP glass laser properties were investigated in the temperature range 80 - 300 K. The highest slope efficiency with respect to absorbed pumped power was 6.1 % at 80 K. The maximum output of peak amplitude power was 0.71 W at 80 K, i.e. 1.2 times higher than at 300 K. Tunability of laser wavelength at 80 K in range 1528 - 1552 nm was obtained using MgF2 birefringent filter. From our measurement it can be concluded, that spectroscopic and laser properties of newly developed Er,Yb:KLaP glass are slightly temperature dependent.
The influence of the phosphorus pentoxide (P2O5) content on the material properties of Er,Yb-doped potassium-lanthanum phosphate glass was studied. Glass samples of the following nominal composition 35.0K2O-6.8Yb2O3-8.0La2O3-0.2Er2O3-50.0P2O5 (in mol%) were prepared from starting materials mixed with five additional amounts of P2O5 (0, 7.5, 15.0, 30.0, and 45.0 mol% related to the nominal glass composition). The P2O5 addition influence on properties of prepared glasses was studied using Raman, absorption, and fluorescence spectroscopy. The glass residual IR absorption and Judd–Ofelt intensity parameters together with absorption and emission cross sections were estimated. The results showed the increasing polymerization of glass and the P─O bond shortening with P2O5 content increase. The spectroscopy of Er3+ and Yb3+ ions was affected only marginally by the glass composition. It was found that fluorescence decay time corresponding to upper-laser-level I413/2 increased with the decrease of P2O5 content in the glasses, which was related to increasing OH− contamination of the glass. The laser action at 1.53 μm under 975-nm pulsed laser diode pumping was successfully demonstrated. Low threshold and laser slope efficiency up to 21% in respect to absorbed pumping power were obtained.
The laser and spectroscopic properties of crystal Er,La:SrF2-CaF2 at temperature range 80 - 300 K, which is appropriate for generation of radiation around 2.7 um is presented. The sample of Er,La:SrF2-CaF2 (concentration Er(0.04), La(0.12):Ca(0.77)Sr(0.07)) had plan-parallel face-polished faces without anti-reflection coatings (thickness 8.2 mm). During spectroscopy and laser experiments the Er,La:SrF2-CaF2 was attached to temperature controlled copper holder and it was placed in vacuum chamber. The transmission and emission spectra of Er,La:SrF2-CaF2 together with the fluorescence decay time were measured in dependence on temperature. The excitation of Er,La:SrF2-CaF2 was carried out by a laser diode radiation (pulse duration 5 ms, repetition rate 20 Hz, pump wavelength 973 nm). Laser resonator was hemispherical, 140 mm in length with at pumping mirror (HR @ 2.7 µm) and spherical output coupler (r = 150 mm, R = 95 % @ 2.5 - 2.8 µm). Tunability of laser at 80 K in range 2690 - 2765 nm was obtained using MgF2 birefringent filter. With decreasing temperature of sample the fluorescence lifetime of manifold 4I11/2 (upper laser level) became shorter and intensity of up-conversion radiation was increasing. The highest slope efficiency with respect to absorbed power was 2.3 % at 80 K. The maximum output of peak amplitude power was 0.3 W at 80 K, i.e. 1.5 times higher than measured this value at 300 K. The wavelength generated by Er,La:SrF2-CaF2 laser (2.7 µm) is relatively close to absorption peak of water (3 µm) and so, one of the possible usage should be in medicine and spectroscopy.
The goal of this work was an investigation of the temperature influence (in range from 80 up to 330 K) on the
laser properties of Er:CaF2 ceramics, which is suitable as a gain medium for generation of radiation at 2.7 μm.
The tested Er:CaF2 ceramics sample, prepared using a hot-forming technique, was doped with 5.5% of ErF3. The
sample was in the form of plane-parallel face-polished 5.8mm thick plate (without AR-coatings). It was mounted
in a temperature controlled cupreous holder, placed inside the vacuum chamber of the liquid nitrogen cryostat.
A fiber coupled laser diode, operating in pulsed regime (3 ms pulse length, 20 Hz repetition rate) at wavelength
968 nm, was used for Er:CaF2 sample pumping. The 145mm long semi-hemispherical laser resonator consisted
of a flat pumping mirror (HR @ 2.65 − 2.95 μm, HT @ 0.97 μm) and a curved (r = 150mm) output coupler
with a reflectivity of ∼ 97% @ 2.65 − 2.85 μm. From the results it follows that the temperature of the active
medium has a strong influence mainly on laser threshold (more than 8 times lower threshold power corresponded
to the temperature 80K in respect to 330 K). The highest slope efficiency (2.3% in respect to absorbed power),
obtained for the temperature 80 K, was more than twice higher than the slope efficiency for 330 K.
The goal of our work was preparation and investigation of Er-doped potassium ytterbium lanthanum orthoand
metha-phosphate glassy mixtures developed as a solid-state laser active medium. The tested samples were
prepared by rapid quenching of molten mixture of starting K2CO3, YbPO4, LaPO4, YbPO4 and P2O5. Their
cations molar concentration was as follows n(K) = 0.7, n(Yb) = 0.135, n(La) = 0.16 and n(Er) = 0.005 and it
was the same in all tested samples. The additions of the P2O5 to the individual starting charges were batched
so the following compositions of resulting glasses should be obtained: (i) pure meta-phosphate, (ii) mixture of
80 mol% of meta-phosphate and 20 mol% of ortho-phosphate, (iii) mixture of 50 mol% of meta-phosphate and
50 mol% of ortho-phosphate, (iv) mixture of 25 mol% of meta-phosphate and 75 mol% of ortho-phosphate, and
(v) pure ortho-phosphate. The glassy samples were prepared in the form of discs about 8mm in diameter and
2mm in height. The absorption spectra were measured in broad range from 200 up to 2500 nm to identify
possible impurities, mainly the residual OH-absorption and to calculate absorption cross-section for pumping
and laser transition 4I15/2 → 4I11/2 and 4I13/2 → 4I15/2, respectively. For particular transitions fluorescence
spectra and fluorescence decay time were recorded simultaneously. It was found that the fluorescence decay
time, corresponding to upper laser level 4I13/2 depopulation, progressively increases with the content of orthophosphate
in glass composition starting from 2ms for sample (i) up to 8ms for sample (iv). The laser action
at 1.54 μm under 975nm pulsed laser diode pumping was successfully demonstrated using the sample with the
longest upper laser level lifetime.
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