Solution-processed chalcogenide glasses (ChGs) are a cost-effective and facile way of fabricating hybrid ChG-silica photonic crystal fibers (PCFs). The bulk glass preparation and the solution-processing of glass are discussed. Optimized annealing conditions are used for assessing the quality of the ChG layers inside PCF holes by using solution-processed Ge-Sb-Se glass film. Finally, the deposition of solution-based ChG layers inside the holes of PCF is demonstrated, which can be used as a platform for various sensor and all-fiber tunable device fabrication and non-linear optical (NLO) applications.
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